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| 光学活性氰醇的不对称合成研究进展 |
| Progress in the Asymmetric Synthesis of Optically Active Cyanohydrins |
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| DOI： |
| 中文关键词: 光学活性 不对称合成 对映异构体 手性催化剂 |
| 英文关键词: optically active asymmetric synthesis enantiomeric isomer chiral catalyst |
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| 中文摘要: |
| 光学活性氰醇是合成大量医药、农药产品的重要中间体。介绍了用具有光学活性的生物或化学催化剂对前手性底物的不对称化来制备光学活性氰醇的方法,重点对(S)-α-氰基-3-苯氧基苯甲醇的不对称催化作了较为全面的概述,并对不对称合成的特点、机理及发展前景作扼要的介绍。 |
| 英文摘要: |
| Optically active cyanohdrins are important intermediates for the synthesis of medical and agricultural chemicals.This article re- views the preparation of optically active cyanohydrins,which are formed by pmchiral suitable substmtes catalyzed by optically active bio- logical or chemical catalysts.And the characteristic,the reaction mechanism and the prospect of asymmetric synthesis were also briefly described in this paper. |
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